
Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Determination of Battery Safety and Performance Parameters Using Adiabatic and Isothermal Calorimetry
FREE Webinar – Thermal Hazard Technology is a proud sponsor of this event.
This presentation describes two main types of calorimetry which can be used to carry out safety and performance testing on batteries. Isothermal calorimeters allow for direct heat measurement on cells during use, while adiabatic calorimeters can measure heat released from batteries during thermal runaway.
Calorimetry can serve as a quantitative scientific method for evaluation of battery safety but it requires appropriate instrumentation. The principles of operation of both types of calorimeters are described along with specific applications within the field of battery testing.
A combination of both technics allows for detailed thermal characterization of lithium-ion and other rechargeable cells, and differences due to chemistry, cell design, cell age, state of charge and cell size can be evaluated.
This webinar will focus on the following key topics:
• The principles of adiabatic and isothermal calorimetry
• How calorimetry can be used in battery testing
• Parameters established by adiabatic safety testing
• Parameters established by isothermal performance testing
• Pressure measurement and gas collection
Presenter
Danny Montgomery – Technical Performance Manager at Thermal Hazard Technology
Danny Montgomery has worked at Thermal Hazard Technology for 9 years. His current role is Technical Performance Manager; overseeing the lab and technical aspects of instrumentation manufactured by THT. He joined the company in 2009 after graduating from Southampton University with a master’s degree in physics.
Danny’s focus is primarily on lithium battery calorimetry; both adiabatic and isothermal. He oversees the use of calorimeters for customer sample testing as well as installing calorimeter systems and provided training for battery and automotive companies worldwide, such as Panasonic, BMW and Samsung. Danny works in Thermal Hazard Technology’s UK office in Milton Keynes.
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Battery Selection Tutorial Course 2/3: Beyond the Standards: Device-Specific Testing
After choosing your cell and manufacturer (Part 1 of this series), most likely, they will have passed the tests of various standards organizations. However, depending on your operating environment, you may need to go above and beyond the baseline to ensure your product operates as intended. This webinar is Part 2 in a three-part series and will review a variety of factors to consider in your device-specific testing, including designing tests to predict the outcomes of various user-abuse scenarios, understanding the mechanisms of gas generation, capacity retention based on different voltage windows, and what happens if you need to cycle your cells outside of their operating range (outside in an Arizona summer or Minnesota winter, for example).
This webinar will focus on the following key topics:
• User-abuse scenarios to prevent against
• Causes and effects of various gas generation mechanisms
• Voltage limits
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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Battery Selection Tutorial Course 3/3: Integrating Your Battery Into Your Product – Designing for Worst-Case Scenarios
The last part in Exponent’s three-part series, this webinar will focus on the finished product from the viewpoint of the battery. How can you best protect your battery within your device? Is your battery going to be user-replaceable? If you’re creating multi-cell packs, how should they be separated from (yet still connected to) each other? Should a thermal event occur, how can you prevent that from cascading through the whole pack? This webinar will help to answer many of those questions, and discuss design questions to help safeguard your battery pack throughout its entire lifecycle.
This webinar will focus on the following key topics:
• Creating multi-cell packs
• Containing thermal runaway events
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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