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Energy Storage RTE Tutorial Course 3/3: Total Battery System RTE – Ranking and Comparison of Different Battery Chemistries
RTE impacts of HVAC/Ventilation and Inverters will be described. Batteries generate heat, and this must be dissipated by system cooling and/or taken out of the system. Heat generated can be calculated by looking at IR heating and that generated (net) by exothermic reactions. Examples will include LFP, Li-NMC, Lead Acid and Nickel batteries, both when they are fresh, as well as at their end of useful life. The overall ancillary equipment energy usage will be listed for these systems, and a % RTE loss will be calculated for both nominal rate and high rate applications. Commentary will be provided for other systems. RTE will be summarized and ranked for most energy storage battery chemistries including ZA, NaS, LiS, Saltwater, Liquid Metal, Zinc Bromine and Fuel Cells.
This webinar will focus on the following key topics:
• RTE impacts of Inverters and HVAC
• RTE impacts for ancillary equipment for different systems
• RTE numbers for most battery systems being considered for energy storage
Presenter
Dr. Halle Cheeseman – Founder/President at Energy Blues LLC
Dr. Halle Cheeseman earned a PhD in Electrochemistry & Corrosion from the University of Nottingham in UK, graduating in 1985. She has held several executive positions in the battery industry over the past 32 years, including Sr. VP of R&D at Spectrum Brands and VP of R&D at Exide Technologies. Her specific battery experience includes Lithium Ion, Zinc Air, Nickel Metal Hydride, Nickel Iron, Alkaline and Lead Acid, focusing on Consumer, Industrial, Automotive & Renewable Energy applications. In July 2017, Dr. Cheeseman founded Energy Blues LLC, an energy storage consulting cooperative comprising 20+ subject matter experts.
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Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Avoid Battery Explosions and Fires – With Right Data and Better Designs
Modern Li Ion batteries contain hazardous chemicals and heat up during use – this combination always has the potential to cause fires and explosions. This presentation will focus on improving the understanding of how such incidents occur, what can be done to avoid them and how the risk can be minimized during early stage design.
The solution lies in knowledge of the heat generation rate during normal use, and information about safe boundaries such as temperature, discharge rate & overcharge in realistic situations that represent actual conditions of use. Data from commercial batteries of different types, including videos of batteries undergoing thermal runaway, will be used to illustrate these points.
A relatively new technique will also be discussed with data, which allows total heat output during discharge to be measured on-line and this can be used both for design and battery modelling. Examples of the data will be provided.
This webinar will focus on the following key topics:
• Why battery fires and explosions occur
• How to design safer batteries through understanding of heat generation
• Video evidence of batteries under explosive conditions
• How better thermal management systems can be designed – based on heat measurement from isothermal calorimetry
• Laboratory instruments suitable for testing and data generation
Presenter
Dr. Jasbir Singh – Managing Director at Hazard Evaluation Laboratory
Jasbir is a chemical engineer specializing in thermal hazards and calorimetry, traditionally for the chemical industry but now increasingly involved in battery safety, especially Li-ion EV and related types.
A graduate of Imperial College (London), where he undertook PhD into combustion and explosions, his experience includes many years in process design for the chemical and petrochemical industries. He is currently developing test methods and instruments for use in design of battery thermal management systems.
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Accelerating Launch of New Battery Technologies by Expediting Samples Through Collaborative Partnerships
Polaris is a processing lab that accelerates new lithium ion battery developments resulting in faster delivery of samples. It provides processing services to accelerate the optimization of recipes for battery developers. Using its services, customers can avoid delays in launching products due to internal funding and staffing constraints.
Services include anode and cathode electrode mix and coat trials, pouch stack cell assemblies, cell and material analytical testing services, business advisory services, and a link to high volume production.
Two major roadblocks facing battery technology companies are addressed: 1) Startups lack staffing, process knowledge, funding, and equipment to develop samples, and 2) Commercialization of new battery technologies is capital intensive and takes long time to pass quality standards
This webinar will focus on the following key topics:
• Significant new material inventions in lithium ion and other advanced battery chemistries in the US
• Two primary issues or “gaps” in getting these technologies to the market
– generating samples for investors, customers and internal engineering evaluation and optimization
– building a battery factory and gaining product and quality system approval (a huge undertaking)
• Polaris Battery Labs Capability Overview for samples and commercialization
• Partner Profile; Carestream Heath as a contract coating partner to reduce time-to-market and risks
Presenter
Doug Morris – CEO – Polaris Battery Labs, LLC
Doug has over 30 years experience in the telecommunications, components, battery, and energy storage industries. Prior to working at Polaris Labs he was VP of Operations at Enevate. Doug has also held various executive, management, and engineering positions over his 21 year career with Motorola where he was VP and Director of Engineering, Quality, and Supply Chain Management for the Energy Systems Group. Doug was also a founder of Motorola’s Product Testing Services business.
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