
Electrochemical Impedance Spectroscopy and Its Application to Battery Analysis
Electrochemical Impedance Spectroscopy (EIS) is a well-established experimental technique that has applications in coatings, corrosion, sensors, electrochemical double layer capacitors, batteries among others. The power of EIS partly comes from its ability to access a very wide range of frequencies (typically from MHz to μHz). For batteries, parameters such as the internal resistance, electrode surface capacitance and leakage are accessible at different frequencies across the spectrum. This allows EIS to gather all the relevant information with a single measurement. In this webinar, we will briefly introduce EIS and cover its application to batteries. We will talk about how to analyze typical data and how to gather the relevant information. We will further talk about available instrumentation and their limitations.
This webinar will focus on the following key topics:
• What is impedance spectroscopy?
• What can impedance spectroscopy do for Battery analysis?
• How can capacitance, internal resistance and leakage be determined using EIS?
• What are the instrumental requirements and limits?
Presenter
Chris Beasley – Gamry Instruments
Chris Beasley received a BS in Chemistry from Kutztown University in 2000 and got a PhD in electrochemistry from University of North Carolina at Chapel Hill in 2010. His doctoral dissertation was on using redox-active nanoparticles as supercapacitors. Chris joined Gamry Instruments in 2010.
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Energy Storage RTE Tutorial Course 3/3: Total Battery System RTE – Ranking and Comparison of Different Battery Chemistries
RTE impacts of HVAC/Ventilation and Inverters will be described. Batteries generate heat, and this must be dissipated by system cooling and/or taken out of the system. Heat generated can be calculated by looking at IR heating and that generated (net) by exothermic reactions. Examples will include LFP, Li-NMC, Lead Acid and Nickel batteries, both when they are fresh, as well as at their end of useful life. The overall ancillary equipment energy usage will be listed for these systems, and a % RTE loss will be calculated for both nominal rate and high rate applications. Commentary will be provided for other systems. RTE will be summarized and ranked for most energy storage battery chemistries including ZA, NaS, LiS, Saltwater, Liquid Metal, Zinc Bromine and Fuel Cells.
This webinar will focus on the following key topics:
• RTE impacts of Inverters and HVAC
• RTE impacts for ancillary equipment for different systems
• RTE numbers for most battery systems being considered for energy storage
Presenter
Dr. Halle Cheeseman – Founder/President at Energy Blues LLC
Dr. Halle Cheeseman earned a PhD in Electrochemistry & Corrosion from the University of Nottingham in UK, graduating in 1985. She has held several executive positions in the battery industry over the past 32 years, including Sr. VP of R&D at Spectrum Brands and VP of R&D at Exide Technologies. Her specific battery experience includes Lithium Ion, Zinc Air, Nickel Metal Hydride, Nickel Iron, Alkaline and Lead Acid, focusing on Consumer, Industrial, Automotive & Renewable Energy applications. In July 2017, Dr. Cheeseman founded Energy Blues LLC, an energy storage consulting cooperative comprising 20+ subject matter experts.
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Battery Selection Tutorial Course 2/3: Beyond the Standards: Device-Specific Testing
After choosing your cell and manufacturer (Part 1 of this series), most likely, they will have passed the tests of various standards organizations. However, depending on your operating environment, you may need to go above and beyond the baseline to ensure your product operates as intended. This webinar is Part 2 in a three-part series and will review a variety of factors to consider in your device-specific testing, including designing tests to predict the outcomes of various user-abuse scenarios, understanding the mechanisms of gas generation, capacity retention based on different voltage windows, and what happens if you need to cycle your cells outside of their operating range (outside in an Arizona summer or Minnesota winter, for example).
This webinar will focus on the following key topics:
• User-abuse scenarios to prevent against
• Causes and effects of various gas generation mechanisms
• Voltage limits
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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Advancing Mining Processes to Make Better Materials for Use in Lithium Ion Batteries
American Manganese Inc has developed a low-cost, environmentally friendly hydrometallurgical process to recover manganese (Mn) from lower grade resources. American Manganese has applied for a patent for their hydrometallurgical process that produces electrolytic manganese metal with low energy and water consumption. American Manganese commissioned R&D contractor, Kemetco Research Inc to determine uses of Artillery Peak manganese resource material to generate high value alternative products. Chemical manganese dioxide (CMD) and lithiated manganese oxide (LixMn2O4) for use in rechargeable batteries were the areas researched.
The research was successful in producing CMD from Artillery Peak resource material with low cation impurities and avoiding processing steps that are known to introduce metallic impurities in the final product. Cation impurities cause capacity fade, whereas metallic impurities are known to cause catastrophic failures (such as fire and explosions) in lithium ion batteries. Working rechargeable lithium ion coin cell battery prototypes were produced from the CMD material.
This webinar will focus on the following key topics:
• Catastrophic failure of Li Ion batteries caused by metallic impurities that may be introduced from the mining of raw materials
• Conventional mining process to recover MnO2 used to make LiMn2O4
• Research on a new mining process that avoids steps known to introduce metallic impurities to recover MnO2 used to make LiMn2O4
Presenter
Norman Chow – President – Kemetco Research, Inc.
Norman earned a B.A.Sc. and M.A.Sc. in Metals and Materials Engineering from University of British Columbia. He is a Registered Professional Engineer (P. Eng.) in British Columbia. He has over 15 years of technology development and contract research experience. He is the President of Kemetco Research Inc., which he formed after acquiring the Industrial Process Division of BC Research Inc. BC Research had been in operation for over 60 years as an R&D contractor.
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