
Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Understand and Prevent Battery Fires and Explosions – and Avoid Costly Failures Like the Samsung Note 7
Modern batteries (eg Li-Ion) contain hazardous chemicals & they heat up during use: this combination always has the potential to cause fires & explosions. This presentation will focus on improving the understanding of how these incidents occur, what can be done to avoid them & how the risk can be minimized during early stage design.
The Samsung Note 7 phone & Boeing Dreamliner airplane fires are very costly examples of how even large corporations fail to understand the potential fire risk of batteries.
The solution lies in knowledge of heat generation rate during normal use & information about safe boundaries such as temperature, discharge rate & overcharge, in realistic situations that represent actual use conditions. Data from commercial batteries of different types will be used to illustrate these points.
A relatively new technique will also be discussed with data, which allows total heat output during discharge to be measured on-line and this can be used both for design and battery modelling. Examples of the data will be provided.
This webinar will focus on the following key topics:
• Why battery fires & explosions occur
• How to design safer batteries though understanding of heat generation
• Video evidence of batteries under explosive conditions
• How better thermal management systems can be designed – based on heat measurement from isothermal calorimetry
• Laboratory instruments suitable for testing and data generation
Presenter
Dr. Jasbir Singh – Managing Director at Hazard Evaluation Laboratory
Jasbir is a chemical engineer specializing in thermal hazards and calorimetry, traditionally for the chemical industry but now increasingly involved in battery safety, especially Li-ion EV and related types.
A graduate of Imperial College (London), where he undertook PhD into combustion and explosions, his experience includes many years in process design for the chemical and petrochemical industries. He is currently developing test methods and instruments for use in design of battery thermal management systems.
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Solid Electrolytes and Bulk Scale Solid-State Batteries
Recently, the push to move beyond Li – ion battery technology has grown. Several advanced battery technologies & chemistries have been identified as promising candidates including i) solid-state batteries with Li metal anode, ii) Li – S chemistries, iii) Li – air(oxygen), and iv) flow batteries. Although an engineered solution using liquids may be possible for some of these options, a solid electrolyte is an enabling technology for each of these beyond Li – ion alternatives. This webinar will introduce the operating principles of each of these cell technologies and solid electrolytes will be discussed in this context. The requirements of a solid electrolyte will be outlined & several state of the art solid electrolytes will be compared. Recent technical progress towards the fabrication of solid-state batteries will be reviewed. Finally, an overview of market applications for solid-state will be presented.
This webinar will focus on the following key topics:
• Overview of beyond Li – ion battery technologies enabled by solid electrolytes
• Comparison of state of the art solid electrolytes
• Recent technical progress towards solid-state batteries
• Review of market applications for solid-state batteries
Presenter
Travis Thompson – Post Doctorate Research Fellow at University of Michigan
Travis received his B.S. in Mechanical Engineering in 2010 from California State Polytechnic University, Pomona, and his PhD in Materials Science at Michigan State University in 2014. His graduate work has focused on synthesis & processing of materials for direct thermal-to-electric energy conversion & storage. This includes ambient drying of silica aerogels, processing of oxide based thermoelectric materials, & electrochemical characterization of ceramic solid electrolytes for advanced batteries. He is now a Research Fellow at The University of Michigan and is exploring commercialization of Solid-State Batteries from his graduate work.
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Battery Selection Tutorial Course 2/3: Beyond the Standards: Device-Specific Testing
After choosing your cell and manufacturer (Part 1 of this series), most likely, they will have passed the tests of various standards organizations. However, depending on your operating environment, you may need to go above and beyond the baseline to ensure your product operates as intended. This webinar is Part 2 in a three-part series and will review a variety of factors to consider in your device-specific testing, including designing tests to predict the outcomes of various user-abuse scenarios, understanding the mechanisms of gas generation, capacity retention based on different voltage windows, and what happens if you need to cycle your cells outside of their operating range (outside in an Arizona summer or Minnesota winter, for example).
This webinar will focus on the following key topics:
• User-abuse scenarios to prevent against
• Causes and effects of various gas generation mechanisms
• Voltage limits
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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