
Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Advancing Mining Processes to Make Better Materials for Use in Lithium Ion Batteries
American Manganese Inc has developed a low-cost, environmentally friendly hydrometallurgical process to recover manganese (Mn) from lower grade resources. American Manganese has applied for a patent for their hydrometallurgical process that produces electrolytic manganese metal with low energy and water consumption. American Manganese commissioned R&D contractor, Kemetco Research Inc to determine uses of Artillery Peak manganese resource material to generate high value alternative products. Chemical manganese dioxide (CMD) and lithiated manganese oxide (LixMn2O4) for use in rechargeable batteries were the areas researched.
The research was successful in producing CMD from Artillery Peak resource material with low cation impurities and avoiding processing steps that are known to introduce metallic impurities in the final product. Cation impurities cause capacity fade, whereas metallic impurities are known to cause catastrophic failures (such as fire and explosions) in lithium ion batteries. Working rechargeable lithium ion coin cell battery prototypes were produced from the CMD material.
This webinar will focus on the following key topics:
• Catastrophic failure of Li Ion batteries caused by metallic impurities that may be introduced from the mining of raw materials
• Conventional mining process to recover MnO2 used to make LiMn2O4
• Research on a new mining process that avoids steps known to introduce metallic impurities to recover MnO2 used to make LiMn2O4
Presenter
Norman Chow – President – Kemetco Research, Inc.
Norman earned a B.A.Sc. and M.A.Sc. in Metals and Materials Engineering from University of British Columbia. He is a Registered Professional Engineer (P. Eng.) in British Columbia. He has over 15 years of technology development and contract research experience. He is the President of Kemetco Research Inc., which he formed after acquiring the Industrial Process Division of BC Research Inc. BC Research had been in operation for over 60 years as an R&D contractor.
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Update on Zinc Hybrid Cathode Battery Technology: Lessons Learned from Demo Projects with Major Utilities in US & Europe
With no economical means to store energy, the utility distribution network has typically been overbuilt and continually expanded to serve peak demand, though only a fraction of that infrastructure is used on an average day.
Working closely with utility partners like AEP and Con Edison, Eos Energy Storage has evaluated the economics of battery storage on the distribution system, with compelling results. Using first-hand knowledge of system costs and specifications, it was found that a utility-owned battery system can break even with a conventional T&D upgrade of ~$5M, or less when monetizing available market revenues.
In this webinar, Eos will share an update on commercialization of its zinc hybrid cathode battery technology and share lessons learned from deployments with major utilities in the US and Europe, from initial business case analysis to commissioning a turnkey product.
This webinar will focus on the following key topics:
• Discuss how energy storage can be leveraged as a utility distribution asset and market resource
• Share Eos’s experience in deploying energy storage systems at utility sites in the US and Europe
• Update on performance and path to commercialization for novel zinc hybrid cathode battery technology
Presenter
Philippe Bouchard – Vice President, Business Development at Eos Energy Storage
Philippe joined Eos after 5 years of in-depth experience leading emerging technology and regulatory initiatives within the utility energy industry. While working previously within Southern California Edison’s Advanced Technology Organization, Philippe co-authored SCE’s Smart Grid Deployment Plan and managed a $3 million portfolio of diversified R&D and technology evaluation projects. Philippe brings an interdisciplinary background in chemistry and environmental sciences, and graduated with a B.A. from Pomona College.
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Battery Selection Tutorial Course 3/3: Integrating Your Battery Into Your Product – Designing for Worst-Case Scenarios
The last part in Exponent’s three-part series, this webinar will focus on the finished product from the viewpoint of the battery. How can you best protect your battery within your device? Is your battery going to be user-replaceable? If you’re creating multi-cell packs, how should they be separated from (yet still connected to) each other? Should a thermal event occur, how can you prevent that from cascading through the whole pack? This webinar will help to answer many of those questions, and discuss design questions to help safeguard your battery pack throughout its entire lifecycle.
This webinar will focus on the following key topics:
• Creating multi-cell packs
• Containing thermal runaway events
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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