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Energy Storage RTE Tutorial Course 2/3: Ampere-Hour (Ah) RTE and Voltage Polarization Energy Losses
Many aqueous systems have water electrolysis to contend with, and above 70-80% SOC, RTE losses from this competing reaction can be significant. Management of these losses has been evolving for decades, and there are now tried and tested methods mostly related to charging algorithms & partial state of charge (pSOC) cycling. These methods will be reviewed. Relevant for every battery chemistry, Cell Voltage factors, will be separated into eight different components, four each, for the cathode and anode. These will be presented & described. The variables that affect them will be reviewed, including the effects of age & cycling and methods for their ongoing measurement. Techniques to reduce and mitigate polarization will be detailed & possible benefits will be quantified in terms of RTE & cost for different scenarios.
This webinar will focus on the following key topics:
• Ah Efficiency losses in aqueous systems
• Types of Voltage Polarization losses for all systems
• Strategies and plans for reducing & mitigating efficiency losses
• Improvement potential for different systems
Presenter
Dr. Halle Cheeseman – Founder/President at Energy Blues LLC
Dr. Halle Cheeseman earned a PhD in Electrochemistry & Corrosion from the University of Nottingham in UK, graduating in 1985. She has held several executive positions in the battery industry over the past 32 years, including Sr. VP of R&D at Spectrum Brands and VP of R&D at Exide Technologies. Her specific battery experience includes Lithium Ion, Zinc Air, Nickel Metal Hydride, Nickel Iron, Alkaline and Lead Acid, focusing on Consumer, Industrial, Automotive & Renewable Energy applications. In July 2017, Dr. Cheeseman founded Energy Blues LLC, an energy storage consulting cooperative comprising 20+ subject matter experts.
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Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Update on Zinc Hybrid Cathode Battery Technology: Lessons Learned from Demo Projects with Major Utilities in US & Europe
With no economical means to store energy, the utility distribution network has typically been overbuilt and continually expanded to serve peak demand, though only a fraction of that infrastructure is used on an average day.
Working closely with utility partners like AEP and Con Edison, Eos Energy Storage has evaluated the economics of battery storage on the distribution system, with compelling results. Using first-hand knowledge of system costs and specifications, it was found that a utility-owned battery system can break even with a conventional T&D upgrade of ~$5M, or less when monetizing available market revenues.
In this webinar, Eos will share an update on commercialization of its zinc hybrid cathode battery technology and share lessons learned from deployments with major utilities in the US and Europe, from initial business case analysis to commissioning a turnkey product.
This webinar will focus on the following key topics:
• Discuss how energy storage can be leveraged as a utility distribution asset and market resource
• Share Eos’s experience in deploying energy storage systems at utility sites in the US and Europe
• Update on performance and path to commercialization for novel zinc hybrid cathode battery technology
Presenter
Philippe Bouchard – Vice President, Business Development at Eos Energy Storage
Philippe joined Eos after 5 years of in-depth experience leading emerging technology and regulatory initiatives within the utility energy industry. While working previously within Southern California Edison’s Advanced Technology Organization, Philippe co-authored SCE’s Smart Grid Deployment Plan and managed a $3 million portfolio of diversified R&D and technology evaluation projects. Philippe brings an interdisciplinary background in chemistry and environmental sciences, and graduated with a B.A. from Pomona College.
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Lithium Ion Capacitors – Combining Energy with Power
FREE Webinar – JSR Micro, Inc. is a proud sponsor of this event.
Lithium Ion Capacitors (LIC) are hybrids of electric double-layer capacitors (EDLCs) and lithium ion batteries (LIB). Combining the reversible non-Faradaic cathode from an EDLC and the reversible Faradaic anode from an LIB results in an ultra or super capacitor with significantly increased energy density, improved float performance and low self-discharge rates. Avoiding the lithium metal oxide cathodes from LIB’s improves the inherent safety and eliminates Cobalt content, however still combines aspects of energy & power of both cell types. The Faradaic intercalation/deintercalation reactions at the anode are capable of generating a significant amount of charge, while the non-Faradaic electrostatic storage of the electrical energy formed at the interface of the electrode and the electrolyte, known as an electric double layer, results in fast charge and discharge capabilities for hundreds of thousands, if not millions of cycles.
This webinar will focus on the following key topics:
• What is an LIC? Technology Introduction
• Key Benefits
• Safety
• EDLC vs LIC
• Applications
Presenter
Jeff Myron – Energy Solutions Program Manager at JSR Micro, Inc.
Since 2011 Jeff has been responsible for business development in North America of JSR group’s environmental energy products including, lithium ion capacitors (LIC) and aqueous battery binders. Jeff joined JSR in 2006 as a Technical Sales Specialist for advanced photoresists utilized in IC manufacturing. Immediately prior to JSR, Jeff worked at Molecular Imprints developing the commercial infrastructure for next generation nano imprint lithography templates. Prior to joining Molecular Imprints, he held various engineering, engineering management & product management positions at Motorola, DuPont Photomask & Brewer Science. Jeff earned a bachelor’s degree in chemistry from Illinois State University in 1990 and an MBA from Webster University in 2001.
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