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Energy Storage RTE Tutorial Course 2/3: Ampere-Hour (Ah) RTE and Voltage Polarization Energy Losses
Many aqueous systems have water electrolysis to contend with, and above 70-80% SOC, RTE losses from this competing reaction can be significant. Management of these losses has been evolving for decades, and there are now tried and tested methods mostly related to charging algorithms & partial state of charge (pSOC) cycling. These methods will be reviewed. Relevant for every battery chemistry, Cell Voltage factors, will be separated into eight different components, four each, for the cathode and anode. These will be presented & described. The variables that affect them will be reviewed, including the effects of age & cycling and methods for their ongoing measurement. Techniques to reduce and mitigate polarization will be detailed & possible benefits will be quantified in terms of RTE & cost for different scenarios.
This webinar will focus on the following key topics:
• Ah Efficiency losses in aqueous systems
• Types of Voltage Polarization losses for all systems
• Strategies and plans for reducing & mitigating efficiency losses
• Improvement potential for different systems
Presenter
Dr. Halle Cheeseman – Founder/President at Energy Blues LLC
Dr. Halle Cheeseman earned a PhD in Electrochemistry & Corrosion from the University of Nottingham in UK, graduating in 1985. She has held several executive positions in the battery industry over the past 32 years, including Sr. VP of R&D at Spectrum Brands and VP of R&D at Exide Technologies. Her specific battery experience includes Lithium Ion, Zinc Air, Nickel Metal Hydride, Nickel Iron, Alkaline and Lead Acid, focusing on Consumer, Industrial, Automotive & Renewable Energy applications. In July 2017, Dr. Cheeseman founded Energy Blues LLC, an energy storage consulting cooperative comprising 20+ subject matter experts.
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Advancing Mining Processes to Make Better Materials for Use in Lithium Ion Batteries
American Manganese Inc has developed a low-cost, environmentally friendly hydrometallurgical process to recover manganese (Mn) from lower grade resources. American Manganese has applied for a patent for their hydrometallurgical process that produces electrolytic manganese metal with low energy and water consumption. American Manganese commissioned R&D contractor, Kemetco Research Inc to determine uses of Artillery Peak manganese resource material to generate high value alternative products. Chemical manganese dioxide (CMD) and lithiated manganese oxide (LixMn2O4) for use in rechargeable batteries were the areas researched.
The research was successful in producing CMD from Artillery Peak resource material with low cation impurities and avoiding processing steps that are known to introduce metallic impurities in the final product. Cation impurities cause capacity fade, whereas metallic impurities are known to cause catastrophic failures (such as fire and explosions) in lithium ion batteries. Working rechargeable lithium ion coin cell battery prototypes were produced from the CMD material.
This webinar will focus on the following key topics:
• Catastrophic failure of Li Ion batteries caused by metallic impurities that may be introduced from the mining of raw materials
• Conventional mining process to recover MnO2 used to make LiMn2O4
• Research on a new mining process that avoids steps known to introduce metallic impurities to recover MnO2 used to make LiMn2O4
Presenter
Norman Chow – President – Kemetco Research, Inc.
Norman earned a B.A.Sc. and M.A.Sc. in Metals and Materials Engineering from University of British Columbia. He is a Registered Professional Engineer (P. Eng.) in British Columbia. He has over 15 years of technology development and contract research experience. He is the President of Kemetco Research Inc., which he formed after acquiring the Industrial Process Division of BC Research Inc. BC Research had been in operation for over 60 years as an R&D contractor.
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Preventing Li Ion Battery Failures From a Manufacturing and Design Perspective
How can you be proactive and make sure your cell supplier is the right one and you don’t end up with thermal events and field failures? Is it enough to qualify a cell manufacturer according to industry standards? The answer is that the majority of compliance based testing is related to abuse tolerance. However, the vast majority of field failures do not occur under abuse scenarios, but happen under normal operating conditions due to manufacturing flaws or design and system tolerance issues that cause internal shorts. In this webinar, you will learn about common lithium ion battery failure modes and how to be proactive in preventing these.
This webinar will focus on the following key topics:
• Gain an understanding of lithium ion battery failure mechanisms and the pathway to thermal events
• Learn how cell design impacts battery safety and reliability
• Learn the basic steps in a lithium ion cell manufacturing process, and how the process controls affect safety and reliability
• Come away with a checklist to qualify your cell manufacturer
Presenter
Vidyu Challa – Technical Director at DfR Solutions
Vidyu Challa is Technical Director at DfR Solutions where she works on battery reliability and safety issues. Dr. Challa helps customers with their battery challenges including design reviews, manufacturing audits and supplier qualification. She obtained a PhD from CALCE Electronic Products and Systems Center at the
University of Maryland. She has broad based expertise that includes engineering technology start-up experience, product development, R&D, and business development. Dr. Challa has published her work in journals, presented at conferences and written blog articles.
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Beyond Electrochemical Analysis – 2D to 4D Correlation of Microstructure and Chemistry in Li-ion Batteries
Single imaging instruments as well as correlative microscopy workflows have demonstrated some unique abilities to support LIB research beyond electrochemical analysis methods. Light microscopy delivers insights about ablation effects & phase orientations in the active material, while scanning electron microscopy (SEM) reveals information about aging effects, nanometer cracks & the composition of the active material. Combining SEM with in-situ Raman spectroscopy extends the traditional SEM capabilities to organic and inorganic material identification. X-ray microscopy, furthermore, delivers 3D non-destructive imaging of full battery packs and localized high-resolution information, thus allowing the identification of regions of interest within the battery material volume. This presentation will demonstrate the application of these techniques to Li-ion battery research, including examples on anode, cathode, binder, and separator materials.
This webinar will focus on the following key topics:
• Introduction to available microscopic investigation techniques
for Li-ion battery research:
– Light Microscopy
– Scanning Electron Microscopy
– X-ray Microscopy
– Raman Spectroscopy
• Review of recent battery imaging studies in published literature
• Case studies on using correlative microscopy to characterize battery performance & failure mechanisms
Presenter
Stefanie Freitag – Market Segment Manager at Carl Zeiss
Stefanie is Market Segment Manager in Materials Research at Carl Zeiss Microscopy in Munich. She holds a Diploma in Engineering Physics, gained first work experiences in a nuclear fusion reactor with a pioneering concept in Greifswald, then worked 3 years in the solar industry in Ulm & Hsinchu, Taiwan. In her current position she analyzes and defines new microscopic solutions for specific materials segments including light microscopy, electron microscopy, x-ray microscopy and chemical methods like Raman spectroscopy.
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