
Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Battery Selection Tutorial Course 1/3: Selecting your Cell and Cell Manufacturer(s)
After designing your product, you need to ensure the battery with which you are operating it will ensure the right performance and lifetime. When deciding this, narrowing down which chemistry (e.g. Li-ion, lithium primary, NiMH, etc.) best fits your product and which form factor are some of the first steps. Choosing a cell design (high-power vs. high-energy, for example) is another step and finally, finding the right cell manufacturer to fabricate your cells and packs. This webinar is the first in a three-part series on designing the right battery for your product. It will cover many of the key differences in chemistries, form factors, and cell designs and other best practices.
This webinar will focus on the following key topics:
• Choosing the right chemistry for your application
• Choosing the right form factor
• Choosing cell designs (e.g. high power vs. high-energy)
Presenter
Exponent – a multidisciplinary engineering and scientific consulting firm with significant experience in various aspects of battery design, safety testing and failure analysis.
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Battery Ageing – How Modeling is Used to Predict Battery Life
Battery modeling and simulation makes it possible to analyze multiple operating conditions and design parameters for batteries and other electrochemical systems and processes. By developing mathematical models you can begin to understand the interaction of electrochemical and chemical processes in the battery and how these processes affect the performance and life of the battery.
In this presentation, we will take a look at the benefits of modeling and simulation in the design, selection, and operation of a lithium-ion battery. We will especially take a look at how modeling can be used together with testing. These results provide manufacturers and application experts with the data to not only predict battery life but to analyze the implications of design parameters and operating conditions to better understand the limitation of the battery.
This webinar will focus on the following key topics:
• Benefits of modeling and simulations in the design, selection, and operation of a lithium-ion battery
• Implications of design parameters and operating conditions with respect to experimental observations of battery performance, aging, and battery safety
• How battery modeling can be used together with testing
Presenter
Tom O’Hara – Global Business Manager, Intertek
Tom O’Hara is the global business manager / advisory services for Intertek’s energy storage programs. Aside from his consulting role, Tom supports U.S. and European marketing and sales efforts and APAC CTIA certification efforts. As a 30-year veteran of the battery technology field, Tom has worked in Energizer Battery’s R&D sector and consulted with several start-up battery companies. He is also the co-inventor of the world’s first successful mercury-free zinc air button cell and holds seven U.S. patents. He obtained both a B.S. and M.S. in chemistry from Wake Forest University in North Carolina.
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Advancing Mining Processes to Make Better Materials for Use in Lithium Ion Batteries
American Manganese Inc has developed a low-cost, environmentally friendly hydrometallurgical process to recover manganese (Mn) from lower grade resources. American Manganese has applied for a patent for their hydrometallurgical process that produces electrolytic manganese metal with low energy and water consumption. American Manganese commissioned R&D contractor, Kemetco Research Inc to determine uses of Artillery Peak manganese resource material to generate high value alternative products. Chemical manganese dioxide (CMD) and lithiated manganese oxide (LixMn2O4) for use in rechargeable batteries were the areas researched.
The research was successful in producing CMD from Artillery Peak resource material with low cation impurities and avoiding processing steps that are known to introduce metallic impurities in the final product. Cation impurities cause capacity fade, whereas metallic impurities are known to cause catastrophic failures (such as fire and explosions) in lithium ion batteries. Working rechargeable lithium ion coin cell battery prototypes were produced from the CMD material.
This webinar will focus on the following key topics:
• Catastrophic failure of Li Ion batteries caused by metallic impurities that may be introduced from the mining of raw materials
• Conventional mining process to recover MnO2 used to make LiMn2O4
• Research on a new mining process that avoids steps known to introduce metallic impurities to recover MnO2 used to make LiMn2O4
Presenter
Norman Chow – President – Kemetco Research, Inc.
Norman earned a B.A.Sc. and M.A.Sc. in Metals and Materials Engineering from University of British Columbia. He is a Registered Professional Engineer (P. Eng.) in British Columbia. He has over 15 years of technology development and contract research experience. He is the President of Kemetco Research Inc., which he formed after acquiring the Industrial Process Division of BC Research Inc. BC Research had been in operation for over 60 years as an R&D contractor.
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