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Energy Storage RTE Tutorial Course 1/3: What is Round Trip Efficiency (RTE)? Why is it Important? How Much Does it Cost?
In the first of this three-part webinar series, a definition of RTE will be presented along with simple system equations that are important to its understanding, determination and management. RTE for some popular battery systems i.e. Lead Acid, Lithium Ion, Vanadium Redox and Nickel Zinc will be computed as examples, and their variation with common variables such as rate, capacity variability & SOC swing will be discussed. The costs of Round Trip inefficiency can be significant, and are experienced by customers either in higher energy generating capital costs and/or higher operating expenses. The calculation of these higher costs will be reviewed, and there will be a discussion on the key industry variables that influence them. Different geographic and customer markets will be considered.
This webinar will focus on the following key topics:
• The Importance of RTE to battery selection decisions
• How does RTE impact CAPEX and/or OPEX for energy storage
• How is RTE defined and how can it be derived – comparison of different systems
• An introduction to ancillary equipment energy losses
Presenter
Dr. Halle Cheeseman – Founder/President at Energy Blues LLC
Dr. Halle Cheeseman earned a PhD in Electrochemistry & Corrosion from the University of Nottingham in UK, graduating in 1985. She has held several executive positions in the battery industry over the past 32 years, including Sr. VP of R&D at Spectrum Brands and VP of R&D at Exide Technologies. Her specific battery experience includes Lithium Ion, Zinc Air, Nickel Metal Hydride, Nickel Iron, Alkaline and Lead Acid, focusing on Consumer, Industrial, Automotive & Renewable Energy applications. In July 2017, Dr. Cheeseman founded Energy Blues LLC, an energy storage consulting cooperative comprising 20+ subject matter experts.
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Beyond Electrochemical Analysis – 2D to 4D Correlation of Microstructure and Chemistry in Li-ion Batteries
Single imaging instruments as well as correlative microscopy workflows have demonstrated some unique abilities to support LIB research beyond electrochemical analysis methods. Light microscopy delivers insights about ablation effects & phase orientations in the active material, while scanning electron microscopy (SEM) reveals information about aging effects, nanometer cracks & the composition of the active material. Combining SEM with in-situ Raman spectroscopy extends the traditional SEM capabilities to organic and inorganic material identification. X-ray microscopy, furthermore, delivers 3D non-destructive imaging of full battery packs and localized high-resolution information, thus allowing the identification of regions of interest within the battery material volume. This presentation will demonstrate the application of these techniques to Li-ion battery research, including examples on anode, cathode, binder, and separator materials.
This webinar will focus on the following key topics:
• Introduction to available microscopic investigation techniques
for Li-ion battery research:
– Light Microscopy
– Scanning Electron Microscopy
– X-ray Microscopy
– Raman Spectroscopy
• Review of recent battery imaging studies in published literature
• Case studies on using correlative microscopy to characterize battery performance & failure mechanisms
Presenter
Stefanie Freitag – Market Segment Manager at Carl Zeiss
Stefanie is Market Segment Manager in Materials Research at Carl Zeiss Microscopy in Munich. She holds a Diploma in Engineering Physics, gained first work experiences in a nuclear fusion reactor with a pioneering concept in Greifswald, then worked 3 years in the solar industry in Ulm & Hsinchu, Taiwan. In her current position she analyzes and defines new microscopic solutions for specific materials segments including light microscopy, electron microscopy, x-ray microscopy and chemical methods like Raman spectroscopy.
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Understand and Prevent Battery Fires and Explosions – and Avoid Costly Failures Like the Samsung Note 7
Modern batteries (eg Li-Ion) contain hazardous chemicals & they heat up during use: this combination always has the potential to cause fires & explosions. This presentation will focus on improving the understanding of how these incidents occur, what can be done to avoid them & how the risk can be minimized during early stage design.
The Samsung Note 7 phone & Boeing Dreamliner airplane fires are very costly examples of how even large corporations fail to understand the potential fire risk of batteries.
The solution lies in knowledge of heat generation rate during normal use & information about safe boundaries such as temperature, discharge rate & overcharge, in realistic situations that represent actual use conditions. Data from commercial batteries of different types will be used to illustrate these points.
A relatively new technique will also be discussed with data, which allows total heat output during discharge to be measured on-line and this can be used both for design and battery modelling. Examples of the data will be provided.
This webinar will focus on the following key topics:
• Why battery fires & explosions occur
• How to design safer batteries though understanding of heat generation
• Video evidence of batteries under explosive conditions
• How better thermal management systems can be designed – based on heat measurement from isothermal calorimetry
• Laboratory instruments suitable for testing and data generation
Presenter
Dr. Jasbir Singh – Managing Director at Hazard Evaluation Laboratory
Jasbir is a chemical engineer specializing in thermal hazards and calorimetry, traditionally for the chemical industry but now increasingly involved in battery safety, especially Li-ion EV and related types.
A graduate of Imperial College (London), where he undertook PhD into combustion and explosions, his experience includes many years in process design for the chemical and petrochemical industries. He is currently developing test methods and instruments for use in design of battery thermal management systems.
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Electrochemical Impedance Spectroscopy and Its Application to Battery Analysis
Electrochemical Impedance Spectroscopy (EIS) is a well-established experimental technique that has applications in coatings, corrosion, sensors, electrochemical double layer capacitors, batteries among others. The power of EIS partly comes from its ability to access a very wide range of frequencies (typically from MHz to μHz). For batteries, parameters such as the internal resistance, electrode surface capacitance and leakage are accessible at different frequencies across the spectrum. This allows EIS to gather all the relevant information with a single measurement. In this webinar, we will briefly introduce EIS and cover its application to batteries. We will talk about how to analyze typical data and how to gather the relevant information. We will further talk about available instrumentation and their limitations.
This webinar will focus on the following key topics:
• What is impedance spectroscopy?
• What can impedance spectroscopy do for Battery analysis?
• How can capacitance, internal resistance and leakage be determined using EIS?
• What are the instrumental requirements and limits?
Presenter
Chris Beasley – Gamry Instruments
Chris Beasley received a BS in Chemistry from Kutztown University in 2000 and got a PhD in electrochemistry from University of North Carolina at Chapel Hill in 2010. His doctoral dissertation was on using redox-active nanoparticles as supercapacitors. Chris joined Gamry Instruments in 2010.
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