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Beyond Electrochemical Analysis – 2D to 4D Correlation of Microstructure and Chemistry in Li-ion Batteries
Single imaging instruments as well as correlative microscopy workflows have demonstrated some unique abilities to support LIB research beyond electrochemical analysis methods. Light microscopy delivers insights about ablation effects & phase orientations in the active material, while scanning electron microscopy (SEM) reveals information about aging effects, nanometer cracks & the composition of the active material. Combining SEM with in-situ Raman spectroscopy extends the traditional SEM capabilities to organic and inorganic material identification. X-ray microscopy, furthermore, delivers 3D non-destructive imaging of full battery packs and localized high-resolution information, thus allowing the identification of regions of interest within the battery material volume. This presentation will demonstrate the application of these techniques to Li-ion battery research, including examples on anode, cathode, binder, and separator materials.
This webinar will focus on the following key topics:
• Introduction to available microscopic investigation techniques
for Li-ion battery research:
– Light Microscopy
– Scanning Electron Microscopy
– X-ray Microscopy
– Raman Spectroscopy
• Review of recent battery imaging studies in published literature
• Case studies on using correlative microscopy to characterize battery performance & failure mechanisms
Presenter
Stefanie Freitag – Market Segment Manager at Carl Zeiss
Stefanie is Market Segment Manager in Materials Research at Carl Zeiss Microscopy in Munich. She holds a Diploma in Engineering Physics, gained first work experiences in a nuclear fusion reactor with a pioneering concept in Greifswald, then worked 3 years in the solar industry in Ulm & Hsinchu, Taiwan. In her current position she analyzes and defines new microscopic solutions for specific materials segments including light microscopy, electron microscopy, x-ray microscopy and chemical methods like Raman spectroscopy.
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Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Preventing Li Ion Battery Failures From a Manufacturing and Design Perspective
How can you be proactive and make sure your cell supplier is the right one and you don’t end up with thermal events and field failures? Is it enough to qualify a cell manufacturer according to industry standards? The answer is that the majority of compliance based testing is related to abuse tolerance. However, the vast majority of field failures do not occur under abuse scenarios, but happen under normal operating conditions due to manufacturing flaws or design and system tolerance issues that cause internal shorts. In this webinar, you will learn about common lithium ion battery failure modes and how to be proactive in preventing these.
This webinar will focus on the following key topics:
• Gain an understanding of lithium ion battery failure mechanisms and the pathway to thermal events
• Learn how cell design impacts battery safety and reliability
• Learn the basic steps in a lithium ion cell manufacturing process, and how the process controls affect safety and reliability
• Come away with a checklist to qualify your cell manufacturer
Presenter
Vidyu Challa – Technical Director at DfR Solutions
Vidyu Challa is Technical Director at DfR Solutions where she works on battery reliability and safety issues. Dr. Challa helps customers with their battery challenges including design reviews, manufacturing audits and supplier qualification. She obtained a PhD from CALCE Electronic Products and Systems Center at the
University of Maryland. She has broad based expertise that includes engineering technology start-up experience, product development, R&D, and business development. Dr. Challa has published her work in journals, presented at conferences and written blog articles.
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Battery EIS Tutorial Course 2/4: EIS at Higher Frequencies for Battery Studies – Good or Bad Indicators for SoC and SoH?
Impedance data at higher frequencies can be used, to some extent, as indicators of the State of Charge (SoC) or State of Health (SoH) of the battery. A discussion of the relevance of this indicator, as well as the most accurate way to determine this value, will be discussed.
This webinar will focus on the following key topics:
• Typical shape of an impedance graph on a battery
• How can it be used for battery monitoring, optimization, and sorting ?
• Various ways to measure this value and our recommendation
Presenter
Dr. Nicolas Murer – Product Manager and Applications Engineer at Bio-Logic SAS, France
Dr. Nicolas Murer is a Product Manager and Applications Engineer at Bio-Logic SAS, France, which designs and manufactures high performance research grade instrumentation and software : potentiostats/galvanostats with built-in Electrochemical Impedance Spectroscopy (EIS), Battery Cyclers, Frequency Response Analyzers for materials analysis, and scanning probe electrochemical workstations. Nicolas received his engineering diploma from Polytechnic Institute of Grenoble in electrochemistry and materials in 2003. He then received his Ph.D. at Université de Bourgogne in 2008. Prior to joining Bio-Logic, he was a post-doctorate at the Ohio State University, Columbus, Ohio (USA).
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