
Stability of Li7La3Zr2O12 Garnet Solid-State Electrolyte Against Metallic Lithium
Energy storage demands will require safer, cheaper and higher performance electrochemical energy storage. While the primary strategy for improving performance has focused on state-of-the-art Li-ion batteries, this work seeks to develop solid-state batteries employing metallic Li anode. Recently, the ceramic electrolyte, Li7La3Zr2O12 (LLZO) cubic garnet, has shown promise owing to its unique combination of properties such as high Li-ion conductivity and electrochemical stability. Generally, LLZO is synthesized through powder processing and sintering at high temperature to produce dense membrane. Processing of the ceramic materials produces internal and surface flaws which will inhibit lithium transport creating localized current density and control the stability against Li dendrite propagation. This presentation will discuss new improvement in methodology to evaluate the integrity of LLZO membrane.
This webinar will focus on the following key topics:
• Methodology to evaluate the integrity of LLZO by identifying the microstructural flaws and their impact on mechanical properties
• DC cycling, EIS, XPS will be shown to determine the reactions that govern the maximum current density
• Correlate the electrochemical stability and critical current density with defects in polycrystalline solid state LLZO electrolyte
Presenter
Asma Sharafi – PhD Student with Jeff Sakamoto at University of Michigan
Asma received her MS in Chemistry (material science) in 2013 at University of Georgia. Currently, she is a PhD student in Mechanical Engineering at University of Michigan under Jeff Sakamoto’s supervision. The primary focus of her research is on the development of new solid state electrolyte (SSE) with the garnet structure (Li7La3Zr2O12) that offer unprecedented safety and durability.
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Preventing Li Ion Battery Failures From a Manufacturing and Design Perspective
How can you be proactive and make sure your cell supplier is the right one and you don’t end up with thermal events and field failures? Is it enough to qualify a cell manufacturer according to industry standards? The answer is that the majority of compliance based testing is related to abuse tolerance. However, the vast majority of field failures do not occur under abuse scenarios, but happen under normal operating conditions due to manufacturing flaws or design and system tolerance issues that cause internal shorts. In this webinar, you will learn about common lithium ion battery failure modes and how to be proactive in preventing these.
This webinar will focus on the following key topics:
• Gain an understanding of lithium ion battery failure mechanisms and the pathway to thermal events
• Learn how cell design impacts battery safety and reliability
• Learn the basic steps in a lithium ion cell manufacturing process, and how the process controls affect safety and reliability
• Come away with a checklist to qualify your cell manufacturer
Presenter
Vidyu Challa – Technical Director at DfR Solutions
Vidyu Challa is Technical Director at DfR Solutions where she works on battery reliability and safety issues. Dr. Challa helps customers with their battery challenges including design reviews, manufacturing audits and supplier qualification. She obtained a PhD from CALCE Electronic Products and Systems Center at the
University of Maryland. She has broad based expertise that includes engineering technology start-up experience, product development, R&D, and business development. Dr. Challa has published her work in journals, presented at conferences and written blog articles.
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Accelerating Launch of New Battery Technologies by Expediting Samples Through Collaborative Partnerships
Polaris is a processing lab that accelerates new lithium ion battery developments resulting in faster delivery of samples. It provides processing services to accelerate the optimization of recipes for battery developers. Using its services, customers can avoid delays in launching products due to internal funding and staffing constraints.
Services include anode and cathode electrode mix and coat trials, pouch stack cell assemblies, cell and material analytical testing services, business advisory services, and a link to high volume production.
Two major roadblocks facing battery technology companies are addressed: 1) Startups lack staffing, process knowledge, funding, and equipment to develop samples, and 2) Commercialization of new battery technologies is capital intensive and takes long time to pass quality standards
This webinar will focus on the following key topics:
• Significant new material inventions in lithium ion and other advanced battery chemistries in the US
• Two primary issues or “gaps” in getting these technologies to the market
– generating samples for investors, customers and internal engineering evaluation and optimization
– building a battery factory and gaining product and quality system approval (a huge undertaking)
• Polaris Battery Labs Capability Overview for samples and commercialization
• Partner Profile; Carestream Heath as a contract coating partner to reduce time-to-market and risks
Presenter
Doug Morris – CEO – Polaris Battery Labs, LLC
Doug has over 30 years experience in the telecommunications, components, battery, and energy storage industries. Prior to working at Polaris Labs he was VP of Operations at Enevate. Doug has also held various executive, management, and engineering positions over his 21 year career with Motorola where he was VP and Director of Engineering, Quality, and Supply Chain Management for the Energy Systems Group. Doug was also a founder of Motorola’s Product Testing Services business.
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Electrochemical Impedance Spectroscopy and Its Application to Battery Analysis
Electrochemical Impedance Spectroscopy (EIS) is a well-established experimental technique that has applications in coatings, corrosion, sensors, electrochemical double layer capacitors, batteries among others. The power of EIS partly comes from its ability to access a very wide range of frequencies (typically from MHz to μHz). For batteries, parameters such as the internal resistance, electrode surface capacitance and leakage are accessible at different frequencies across the spectrum. This allows EIS to gather all the relevant information with a single measurement. In this webinar, we will briefly introduce EIS and cover its application to batteries. We will talk about how to analyze typical data and how to gather the relevant information. We will further talk about available instrumentation and their limitations.
This webinar will focus on the following key topics:
• What is impedance spectroscopy?
• What can impedance spectroscopy do for Battery analysis?
• How can capacitance, internal resistance and leakage be determined using EIS?
• What are the instrumental requirements and limits?
Presenter
Chris Beasley – Gamry Instruments
Chris Beasley received a BS in Chemistry from Kutztown University in 2000 and got a PhD in electrochemistry from University of North Carolina at Chapel Hill in 2010. His doctoral dissertation was on using redox-active nanoparticles as supercapacitors. Chris joined Gamry Instruments in 2010.
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